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Carbenoid

In chemistry a carbenoid is a reactive intermediate that shares reaction characteristics with a carbene. In the Simmons-Smith reaction the carbenoid intermediate is a zinc / iodine complex that takes the form of

I-CH2-Zn-I

This complex reacts with an alkene to a cyclopropane just as a carbene would do.

References



08-19-2006 15:59:36
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